To avoid bothering your friends or hiding your Facebook profile, leaving you unaware of when they're online, I'll guide you on receiving notifications when your friends are online on Facebook using your computer.
Step 1: Download MonokaiToolkit here and unzip the downloaded folder.
Step 2: Open the Chrome browser, click on the three dots in the upper right corner, select 'More tools,' and then choose 'Extensions.'

Step 3: Slide the top right corner to activate 'Developer mode,' designed for developers.

Step 4: Click 'Load unpacked,' choose the MonokaiToolkit folder, and press 'Select Folder' to install.

Step 5: Log into your Facebook on Chrome, click the extension icon in the top right corner, then click 'Sign in' and re-enter your password. The extension won't store any data or information about your Facebook account.

Step 6: Select 'Add Target,' then choose the person you want to track and click 'OK.' To unfollow someone, click on the person, select 'Operations,' and choose 'Remove this target.'

Step 7: Finally, go to 'Settings,' enable 'Notifications' to activate the extension's notification feature.

That's it! With just a few simple steps, you can now receive notifications when your friends are online on Facebook. Wishing you a successful implementation.
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